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新《生活饮用水卫生标准》GB5749-项目解读(4)锑
2008年09月22日  来源:中国滤材网  [进入论坛讨论]  编辑:ヤo_o灀懵蝶

一、水质指标
   详见
二、锑的化学性质
【中文名称】锑
【英文名称】antimony
【结构或分子式】
【相对分子量或原子量】121.760
【密度】6.684
【熔点(℃)】630.5
【沸点(℃)】1635
【性状】
有金属变体和黄色变体两种同素异形体,前者有银白色金属光泽,具有鲜明的晶体结构。
【溶解情况】
不溶于水、盐酸和碱溶液,溶于王水、浓硫酸,以及硝酸和酒石酸的混合液。
【用途】
主要供制印刷合金、巴比合金、锑盐和颜料、蓄电池、白冰铜、硬质合金、轴承合金。也用于半导体工业。
【制备或来源】
自然界所产的锑大多数是灰锑矿。可将灰锑矿与铁粉混合共热而取代出锑,或煅烧成氧化物后再与碳共热而使氧化物还原成锑。
【其他】
原子序数51,原子量121.760,化合价+3、-3、+5、-5。高温时煅烧成氧化物,为两性氧化物。
氧化物离解能(Do):3.2(eV)
元素电离能(Ei): 8.64(eV)
主要吸收线及其主要参数:
│λ(nm)   │  f   │ W  │  F │ S*   │  CL  │ R·S │
│206.8   │0.1   │ 0.2│A-A │0.5   │      │1.0   │
│217.6   │0.045 │ 0.2│A-A │1.1   │      │2.2  │
│231.2   │0.03  │ 0.2│A-A │1.9   │      │4.0  │
│221.7   │      │ 0.2│A-A │      │      │     │
 
λ:波长
f:振子强度
W:单色器光谱通带
A- A(空气乙炔焰)
S*:元素的特征浓度(1%吸收灵敏度)
CL:元素的检测极限
R·S:同一元素主要吸收线间的相对灵敏度
F:火焰类型
 
三、锑的来源
Antimony has been known since ancient times. It is sometimes found free in nature, but is usually obtained from the ores stibnite (Sb2S3) and valentinite (Sb2O3). Nicolas Lémery, a French chemist, was the first person to scientifically study antimony and its compounds. He published his findings in 1707. Antimony makes up about 0.00002% of the earth's crust.
Antimony is a brittle metal and is a poor conductor of heat and electricity. Very pure antimony is used to make certain types of semiconductor devices, such as diodes and infrared detectors. Antimony is alloyed with lead to increase lead's durability. Antimony alloys are also used in batteries, low friction metals, type metal and cable sheathing, among other products. Antimony compounds are used to make flame-proofing materials, paints, ceramic enamels, glass and pottery. The ancient Egyptians used antimony, in the form of stibnite, for black eye make-up. 
 
四、锑对健康的影响
Antimony occurs naturally in the environment. But it also enters the environment through several applications by humans. Especially people that work with antimony can suffer the effects of exposure by breathing in antimony dusts. Human exposure to antimony can take place by breathing air, drinking water and eating foods that contain it, but also by skin contact with soil, water and other substances that contain it. Breathing in antimony that is bond to hydrogen in the gaseous phase, is what mainly causes the health effects.
Exposure to relatively high concentrations of antimony (9 mg/m3 of air) for a longer period of time can cause irritation of the eyes, skin and lungs.
As the exposure continues more serious health effects may occur, such as lung diseases, heart problems, diarrhea, severe vomiting and stomach ulcers.
It is not known whether antimony can cause cancer or reproductive failure.
Antimony is used as a medine for parasital infections, but people who have had too much of the medicine or were sensitive to it have experienced health effects in the past. These health effects have made us more aware of the dangers of exposure to antimony.
 
五、锑对环境的影响  
Antimony can be found in soils, waters and air in very small amounts. Antimony will mainly pollute soils. Through groundwater it can travel great distances towards other locations and surface waters.
Laboratory tests with rats, rabbits and guinea pigs have shown us that relatively high levels of antimony may kill small animals. Rats may experience lung, heart, liver and kidney damage prior to death.
Animals that breathe in low levels of antimony for a long time may experience eye irritation, hair loss and lung damage. Dogs may experience heart problems even when they are exposed to low levels of antimony. Animals that breathed in low levels of antimony for a couple of months may also experience fertility problems.
Whether antimony can cause cancer has not been fully specified yet.
 
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